Review of Conversion Technologies of Waste Polystyrene into useful Products

Authors

  • Shalu Patel M. Tech, Department of Energy Center, Maulana Azad National Institute of Technology, Bhopal, (M.P), India
  • Shalu Patel M. Tech, Department of Energy Center, Maulana Azad National Institute of Technology, Bhopal, (M.P), India
  • Savita Dixit Professor and Head ,Department of Chemistry , Maulana Azad National Institute of Technology, Bhopal, (M.P), India
  • Kavita Gidwani Suneja Assistant Professor, Department of Energy Center, Maulana Azad National Institute of Technology, Bhopal, (M.P), India
  • Nilesh Tipan PhD Scholar, Department of Mechanical Engineering, Maulana Azad National Institute of Technology, Bhopal (M.P), India

DOI:

https://doi.org/10.24113/ijoscience.v7i3.372

Abstract

Polystyrene usage has risen significantly in recent years as a result of its wide variety of applications. The persistent consumer demand for polystyrene resulted in the accumulation of polystyrene waste in landfills, inducing environmental degradation. Since polystyrene is a petroleum-derived material, the increasing demand for it resulted in the depletion of petroleum, a non-renewable energy source. Research teams from all over the world have invented many methods for dealing with polystyrene waste, including recycling and energy regeneration. However, there are drawbacks to recycling methods, such as the fact that they need a lot of manpower in the separating procedure and pollute the water, reducing the process's sustainability. Because of these flaws, the experimenters have cantered their efforts on the energy harvesting approach. As petroleum is the primary component of polystyrene, the pyrolysis process for recovering fuel oil from polystyrene is an useful technology because the retrieved oil has a higher calorific value than commercially available gasoline. The current paper discusses polystyrene conversion technologies as well as the pyrolysis techniques for polystyrene, which generates end products such as oil, gas, and char. The impact of different processing parameters on the product yield has been addressed using more advanced techniques of conducting pyrolysis with a solvent.

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References

Geyer, R.; Jambeck, J.R.; Law, K.L. Production, use, and fate of all plastics ever made. Sci. Adv. 2017, 3.

Euractiv. Available online: https://www.euractiv.com/ (accessed on 27 July 2019).

U.S. Environmental Protection Agency. EPA Textiles—Common Wastes and Materials; U.S. Environmental Protection Agency: Washington, DC, USA, 2014.

European-Plastics. An Analysis of European Plastics Production, Demand and Waste Data; European-Plastics: Brussels, Belgium, 2015.

Webb, H.K.; Arnott, J.; Crawford, R.J.; Ivanova, E.P. Plastic degradation and its environmental implications with special reference to poly(ethylene terephthalate). Polymers 2013, 5, 1–18.

Ungureanu, O.I.; Bulgariu, D.; Mocanu, A.M.; Bulgariu, L. Functionalized PET waste based low-cost adsorbents for adsorptive removal of Cu(II) ions from aqueous media. Water 2020, 12, 2624.

Kukreja, R. Advantages and Disadvantages of Recycling 9–10. Conserve Energy Future. 2009. Available online: https://www. conserve-energy-future.com/advantages-and disadvantages-of-recycling.php (accessed on 27 July 2019).

Bajdur,W.;Pajczkowska,J.;Makarucha,B.;Sulkowska,A.;Sulkowski,W.W.Effectivepolyelectrolytessynthesisedfromexpanded polystyrene wastes. Eur. Polym. J. 2002, 38, 299–304.

Vilaplana, F.; Ribes-Greus, A.; Karlsson, S. Degradation of recycled high-impact polystyrene. Simulation by reprocessing and thermo-oxidation. Polym. Degrad. Stab. 2006, 91, 2163–2170. Vilaplana, F.; Ribes-Greus, A.; Karlsson, S. Degradation of recycled high-impact polystyrene. Simulation by reprocessing and thermo-oxidation. Polym. Degrad. Stab. 2006, 91, 2163–2170.

Panda,A.K.;Singh,R.K.;Mishra,D.K.ThermolysisofwasteplasticstoliquidfuelAsuitablemethodforplasticwastemanagement and manufacture of value added products—A world prospective. Renew. Sustain. Energy Rev. 2010, 14, 233–248.

Chauhan,R.S.;Gopinath,S.;Razdan,P.;Delattre,C.;Nirmala,G.S.;Natarajan,R.Thermaldecompositionofexpandedpolystyrene in a pebble bed reactor to get higher liquid fraction yield at low temperatures. Waste Manag. 2018, 28, 2140–2145.

Liu, Y.; Qian, J.; Wang, J. Pyrolysis of polystyrene waste in a ?uidized-bed reactor to obtain styrene monomer and gasoline fraction. Fuel Process. Technol. 2000, 63, 45–55.

Hwang, G.C.; Choi, J.H.; Bae, S.Y.; Kumazawa, H. Degradation of Polystyrene in Supercritical n-Hexane. KoreanJ.Chem. Eng. 2011, 18, 854–861.

Arandes,J.M.;Ereña,J.;Azkoiti,M.J.;Olazar,M.;Bilbao,J.Thermalrecyclingofpolystyreneandpolystyrene-butadienedissolved in a light cycle oil. J. Anal. Appl. Pyrolysis 2003, 70, 747–760.

Karaduman, A.; Ims¸ek, E.H.; Çiçek, B.; Bilgesü, A.Y. Thermal degradation of polystyrene wastes in various solvents. J. Anal. Appl. Pyrolysis 2012, 62, 273–280.

Dong, D.; Tasaka, S.; Inagaki, N. Thermal degradation of monodisperse polystyrene in bean oil. Polym. Degrad. Stab. 2017, 72, 345–351.

Ahmad, Z.; Al-Sagheer, F.; Al-Awadi, N.A. Pyro-GC/MS and thermal degradation studies in polystyrene-poly(vinyl chloride) blends. J. Anal. Appl. Pyrolysis 2010, 87, 99–107.

Chumbhale, V.R.; Kim, J.S.; Lee, S.B.; Choi, M.J. Catalytic degradation of expandable polystyrene waste (EPSW) over mordenite and modi?ed mordenites. J. Mol. Catal. A Chem. 2004, 222, 133–141.

Ukei, H.; Hirose, T.; Horikawa, S.; Takai, Y.; Taka, M.; Azuma, N.; Ueno, A. Catalytic degradation of polystyrene into styrene and a design of recyclable polystyrene with dispersed catalysts. Catal. Today 2000, 62, 67–75.

Kim, J.S.; Lee, W.Y.; Lee, S.B.; Kim, S.B.; Choi, M.J. Degradation of polystyrene waste over base promoted Fe catalysts. Catal. Today 2003, 87, 59–68.

Marczewski, M.; Kamin´ska, E.; Marczewska, H.; Godek, M.; Rokicki, G.; Soko?owski, J. Catalytic decomposition of polystyrene. The role of acid and basic active centers. Appl. Catal. B Environ. 2013, 129, 236–246.

Shah, J.; Jan, M.R. Adnan Catalytic activity of metal impregnated catalysts for degradation of waste polystyrene. J. Ind. Eng. Chem. 2014, 20, 3604–3611.

Vilaplana, F.; Ribes-Greus, A.; Karlsson, S. Degradation of recycled high-impact polystyrene: Simulation by reprocessing and thermooxidation. Polym. Degrad. Stab. 2006, 91, 2163–2170.

Toyomasa, M. Patent number JP2004142235, 2004. 4. David, C.; Steven, M.L.; Edmond, C.J. Patent number EP1325066, 2003. 5. Marcello, N.; Franco, R. Patent number WO2005023922, 2015.

David, C.; Steven, M.L.; Edmond, C.J. Patent number EP1325066, 2003

Marcello, N.; Franco, R. Patent number WO2005023922, 2015.

Koji, U.; Yoshio, M.; Naoto, A.; Tamaki, H.; Sanae, H.; Mitsunori, O. Patent number JP10130418, 2008.

Ke, H.; Li-hua, T.; Zi-Bin, Z.; Cheng-Fang, Z. Reaction mechanism of styrene monomer recovery from waste polystyrene by supercritical solvents. Polym. Degrad. Stab. 2015, 89, 312–316.

Bhaskar, T.; Uddin, M.A.; Murai, K.; Kaneko, J.; Hamano, K.; Kusaba, T.; Muto, A.; Sakata, Y. Comparison of thermal degradation products from real municipal waste plastic and model mixed plastics. J. Anal. Appl. Pyrol. 2003, 70, 579–587.

Ross, S.; Evans, D. The environmental effect of reusing and recycling a plastic-based packaging system. J. Clean Prod. 2003, 11, 561–571. 16.

Scott, D.S.; Czernik, S.R.; Piskorz, J.; Radlein, A.G. Fast pyrolysis of plastic wastes. Energ. Fuels 2016, 4, 407–411.

Conesa, J.A.; Marcilla, A.; Font, R. Kinetic model of the pyrolysis of polyethylene in a fluidized bed reactor. J. Anal. Appl. Pyrol. 2014, 30, 101–120.

Mehta, S.; Biederman, S.; Shivkumar, S. Thermal degradation of foamed polystyrene. J. Mater Sci. 2016, 30, 2944–2949.

Uemichi, Y.; Hattori, M.; Itoh, T.; Nakamura, J.; Sugioka, M. Deactivation behaviors of zeolite and silica-alumina catalysts in the degradation of polyethylene. Ind. Eng. Chem. Res. 2011, 37, 867–872.

Kiran, N.; Ekinci, E.; Snape, C.E. Recycling of plastic wastes via pyrolysis. Resour. Conservat. Recycl. 2015, 29, 273–283.

White, K.L.; Wight, H.B. Treatment of Waste and a Rotary Kiln Therefor. International Patent Application No. WO1988002284A1, 7 April 2018.

Northemann, A.D. Process for the Recovery of Styrene from Used Polystyrene. U.S. Patent US5672794A, 29 August 2016.

Bouziane, R. Batch Process for Recycling Hydrocarbon Containing Used Materials. U.S. Patent US5821396A, 13 October 2008.

Matsubayashi, I. Recovery System of Styrene-Containing Liquid and Recovering Method. J.P. Patent No. JP2005314315A, 10 November 2005.

Yang, Y. Process and Eqipment for Treatment of Waste Plastics. U.S. Patent No. US5811606A, 22 September 2008.

Carner, W.E. System and Method for Recycling Plastics. U.S. Patent No. US7892500B2, 18 November 2009.

Srinakruang, J. Process for Producing Fuel from Plastic Waste Material by Using Dolomite Catalyst. U.S. Patent No. US8344195B2, 1 January 2013.

De Whitt, K.C. System for Recycling Plastics. International Patent Application No. PCT/US2010/040219, 28 June 2010.

McNamara, D.; Murray, M. Conversion of Waste Plastics Material to Fuel. U.S. Patent No. US20120261247A1, 18 October 2012.

Bordynuik, J.W. System and Process for Converting Plastics to Petroleum Products. International Patent Application No. WO2013015819A1, 31 January 2013.

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Published

03/27/2021

How to Cite

Patel, S. ., Patel, S. ., Dixit, S. ., Suneja, K. G. ., & Tipan, N. (2021). Review of Conversion Technologies of Waste Polystyrene into useful Products. SMART MOVES JOURNAL IJOSCIENCE, 7(3), 43–48. https://doi.org/10.24113/ijoscience.v7i3.372

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